Course manual 2017/2018

Course content

A broad range of important homogeneous catalytic reactions will be discussed. Emphasis will be on transition metal catalyzed reactions. Important aspects like mechanistic studies, kinetics, and effects of the nature of the metal ion and ligand structure will be explained. Processes that are applied industrially are discussed more in-depth. The important role of homogeneous catalysis in organic synthesis will be illustrated. Active student participation.

Study materials

Literature

  • P.W.N.M. van Leeuwen, 'Homogeneous Catalysis; Understanding the Art'.

Objectives

The subject of this course is learning about the molecular approach in the development of homogeneous catalysts for applications in laboratory and industry. At the end of the course the student is able to discuss catalytic reaction mechanisms for a variety of discussed reaction types and derivatives thereof, suggest plausible experiments and techniques to gain mechanistic insight, analyze and interpret spectroscopic and kinetic data to evaluate mechanisms and to deduce likely pathways for reactions, provide suggestions related to ligand and catalyst optimization, comment on the various selectivity issues related to homogeneous catalysis and elaborate on similarities and differences between different types of catalytic reactions and the metal complexes used therein.

 

Teaching methods

  • Lecture
  • Self-study

Lectures, literature.

Learning activities

Activity

Number of hours

Zelfstudie

168

Attendance

The programme does not have requirements concerning attendance (OER-B).

Assessment

Item and weight Details

Final grade

1 (100%)

Tentamen

Inspection of assessed work

Contact the course coordinator to make an appointment for inspection.

Fraud and plagiarism

The 'Regulations governing fraud and plagiarism for UvA students' applies to this course. This will be monitored carefully. Upon suspicion of fraud or plagiarism the Examinations Board of the programme will be informed. For the 'Regulations governing fraud and plagiarism for UvA students' see: www.student.uva.nl

Timetable

The schedule for this course is published on DataNose.

Additional information

Recommended prior knowledge (but not compulsory):  MSc Organometallic Chemistry (or at least BSc Organometallic Chemistry).

Contact information

Coordinator

  • dr. ir. J.I. van der Vlugt